Kalck P. (ed.) Modes of Cooperative Effects in Dinuclear Complexes

Springer Nature Switzerland AG, 2023. — 240 p. — ISBN: 978-3-031-32249-5. — Topics in Organometallic Chemistry №70.This book presents recent advances in dinuclear complexes in which the metal-metal cooperative effect operates for obtaining substrate activation and high performance catalysts. Catalysis continues to be a fast expanding area to design efficient tools in synthesis and in industrial chemistry. It allows performing syntheses with short reaction times, atom economy, reduced consumption of energy and loss of reagents, and low level of wastes. Dinuclear complexes are known to be more efficient than the mononuclear analogues for the reaction rates and the selectivities. This book analyses the latest research, focusing on the key concepts, in building and using these dinuclear complexes. The book is aimed at researchers, graduate students and chemists at all levels in academia and industry.Dinuclear Reactivity of One Metal Exalted by the Second One
Chemical Transformations in Heterobimetallic Complexes Facilitated by the Second Coordination Sphere
Role of a Redox-Active Ligand Close to a Dinuclear Activating Framework
Dinuclear Reactivity Between the Two Metal Centers
Magnetism in Binuclear Compounds: Theoretical Insights