Gómez Gallego M., Sierra M.A. Organic Reaction Mechanisms

Berlin, Heidelberg: Springer-Verlag, 2004. — 288 p. — ISBN: 978-3-642-18788-9 (eBook)
40 Solved Cases. With 432 figures, 116 in colour.A Surprise in the Synthesis of Guanacastepene A.
Sulfenylation of Indole.
Substrate Selective Reactions in the Presence of Lewis Acids.
Diastereoselective Reductions of betta-Ketoesters.
Rearrangements from Tetrahydropyran Derivatives.
Stereospecific Substitution Reactions of Epoxy Sulfides.
NaBH4 Reduction of alfa,betta-Unsaturated Chromium Carbene Complexes.
Addition of Hydroxylamines to alfa,betta-Unsaturated Esters.
Solvolysis of Electron-Deficient Norbornyl Triflates.
Nucleophile Versus Base Catalysis.
The Hydrolysis of p-Substituted Styrene Oxides.
Elimination Reactions of Benzaldehyde O-Benzoyloximes.
Oxygen Versus Sulfur Stabilization of Carbenium Ions.
Cyclization of 2,3-Dibenzylidenesuccinates.
Oxazoline N-Oxides as Dipoles in [3+2] Cycloadditions.
Light-Induced Cycloadditions of N-Phthaloyl alfa-Amino Acids.
Change in Rate-Determining Step in an E1cB Mechanism: Aminolysis of Sulfamate Esters.
Unusual Diels-Alder Reactivity of Acyclic 2-Azadienes.
Chelate-Controlled Carbonyl Addition Reactions.
Esterification of Carboxylic Acids with Dimethyl Carbonate and DBU.
A Hammett Analysis in a Multistep Reaction: Rhodium(II)-Catalyzed Decomposition of alfa-Diazo Esters.
Tandem Cycloadditions with Nitronates.
Hydrolysis of 2-Aminobenzoate Esters.
Rearrangements of Cyclobutenones.
Epoxi Ester-Orthoester Rearrangement.
2-Chloro-1,3,5-triazines as Activating Groups of Carboxylic Acids in the Formation of Peptide Bonds.
Acid-Catalyzed Isomerization of Imines.
A Dearomatizing Disrotatory Electrocyclic Ring Closure.
Stereoselective Debromination of Vicinal Dibromides.
Diels-Alder Reactions of N-Acyl-1,2,4,5-tetrazines.
Stereoselective Synthesis of 2-Acylaziridines.
The Baylis-Hillman Reaction.
The Rate-Determining Step in the SNAr Reaction.
Helicenophanes and their Racemization.
Solvolysis of Vinyl Iodonium Salts.
Vicarious Nucleophilic Substitution.
Base-promoted HF Elimination from 4-Fluoro-4-(4´-nitrophenyl)butan-2-one.
Substitution of betta-Halostyrenes by MeS–.
Periodinane-Mediated Cyclization of Anilides.
Solvolysis of 8-Deltacyclyl Brosylates.